Nathan for You (Comedy Central, 10:00 p.m.) — In the season three premiere of his critically acclaimed comedy series, Nathan Fielder helps the struggling owner of a small electronics store throw Best Buy’s price-match policy right back in its face.
The Blacklist (NBC, 9:00 p.m.) — Red and Liz are still on the lam. This week, they head to the flyover states with Samar and Aram still tracking them, but trying to solve a possible global food crisis in the process. Maybe they’re the team who prevented that Eggo shortage. Remember that? What a terrifying time to be alive…
Scandal (ABC, 9:00 p.m.) — Jake sees a blast from the past (and we don’t mean that awesomely terrible Brendan Fraser movie), while Huck and Quinn call in some familiar reinforcements to help Olivia weather a media storm.
How to Get Away with Murder (ABC, 10:00 p.m.) — Don’t. Go. In. The. Woods. At. Night. How difficult is that rule for people to abide by? Annalise and her team defend a suspect after a girl is found murdered in the woods, but did the big, bad wolf actually do it?
MLB Postseason (TBS, 8:00 p.m.) — Win or go home. Last year’s NL Rookie of the Year Jacob deGrom and 2015 NL Cy Young hopeful Zack Greinke face off as the Mets and Dodgers play for keeps in Game 5 of the NLDS.
The Vampire Diaries (The CW, 8:00 p.m.) — Peace negotiations can get really complicated. Damon learns this the hard way when he undermines a deal between Stefan and Lily and has to pay the price for it.
Bones (FOX, 8:00 p.m.) — Bones and Booth go back to work. (Do you feel those first-day-of-school butterflies, yet?) Oh, and a hollowed out dead guy turns out to be the smelliest piece of flesh at a fish market, so Angela’s got to track down his missing organs.
Heroes Reborn (NBC, 8:00 p.m.) — Tommy’s probably got Styx lyrics looping in his head as the jig is up because authorities are closing in. Meanwhile, Miko’s too focused on retrieving her sword to notice that she might be putting herself in danger.
Sleepy Hollow (FOX, 9:00 p.m.) — Pandora’s box is open and that is definitely not a euphemism, here. A terrifying artifact has been released that can turn humans into something scarier, which is nearly impossible to fathom considering how terrible humans can be to each other, ya know?
Benders (IFC, 10:00 p.m.) — The guys pretend to be religious to get in the good graces of a Christian team from D7. Good luck making it more than 30 seconds without swearing, guys.
Thursday Night Football (CBS, 8:25 p.m.) — The undefeated Falcons look to move to 6-0 against Drew Brees and the Saints.
LATE NIGHT GUESTS: Oprah, Joseph Fink & Jeffrey Cranor and Judith Hill on Colbert; Cindy Crawford, Matt Bomer and Raury on Corden; Jack Black on The Daily Show; Tom Hanks, Jessica Chastain and Pentatonix on Fallon; Justin Theroux, Scott Foley and Duran Duran on Kimmel; Zooey Deschanel, Dominic West and Nathan Fielder on Meyers.